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1.
Maryam S. Sadeghi Mohammad Reza Moghbeli William A. Goddard III 《Journal of polymer science. Part A, Polymer chemistry》2021,59(7):614-626
We followed the self-assembly of high-molecular weight MePEG- b -PCL (poly(methyl ethylene glycol)-block-poly(ε-caprolactone)) diblock and MePEG- b -PBO- b -PCL (poly(methyl ethylene glycol)-block-poly(1,2-butylene oxide)-block-poly(ε-caprolactone)) into micelles using molecular dynamics simulation with a coarse grain (CG) force field based on quantum mechanics (CGq FF). The triblock polymer included a short poly(1,2-butylene oxide) (PBO) at the hydrophilic-hydrophobic interface of these systems. Keeping the hydrophilic length fixed (MePEG45), we considered 250 chains in which the hydrophobic length changed from PCL44 or PBO6- b -PCL43 to PCL62 or PBO9- b -PCL61. The polymers were solvated in explicit water for 2 μs of simulations at 310.15 K. We found that the longer diblock system undergoes a morphological transition from an intermediate rod-like micelle to a prolate-sphere, while the micelle formed from the longer triblock system is a stable rod-like micelle. The two shorter diblock and triblock systems show similar self-assembly processes, both resulting in slightly prolate-spheres. The dynamics of the self-assembly is quantified in terms of chain radius of gyration, shape anisotropy, and hydration of the micelle cores. The final micelle structures are analyzed in terms of the local density components. We conclude that the CG model accurately describes the molecular mechanisms of self-assembly and the equilibrium micellar structures of hydrophilic and hydrophobic chains, including the quantity of solvent trapped inside the micellar core. 相似文献
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3.
Experimental study on age and gender differences in microscopic movement characteristics of students 下载免费PDF全文
《中国物理 B》2021,30(9):98902-098902
Campus security has aroused many concerns from the whole society. Stampede is one of the most frequent and influential accidents in campus. Studies on pedestrian dynamics especially focusing on students are essential for campus security, which are helpful to improve facility design and emergency evacuation strategy. In this paper, primary and middle school students were recruited to participate in the single-file experiments. The microscopic movement characteristics,including walking speed, headway, gait characteristics(step length, step frequency and swaying amplitude) and their relations were investigated. Age and gender differences in the headway-speed diagram and space requirements were analyzed by statistical tests. The results indicated that the impacts of age and gender were significant. There were three stages for the influence of gender on the headway-speed diagram for both age groups. The impacts on students' space requirements were consistent for different age and gender groups. But the impacts of age and gender on free-flow speed were affected by each other. Due to the connection of walking speed and gait characteristics, the comparisons of gait characteristics between different ages and genders were performed to understand the corresponding differences in speed more deeply. The results showed that differences in step length and swaying amplitude between males and females were significant for both age groups. The effect of gender on step frequency was significant for primary students. But for middle school students,whether gender had significant impact on step frequency was not clear here because of the large P-value. Besides, the influence of age on gait characteristics changed with gender. 相似文献
4.
三氧化二铋(Bi2O3)是氧离子导电体,为了获得它的原子热振动各向同性温度因子,对该粉末晶体进行X射线衍射实验,建立了晶体结构模型,利用Rietveld 精修方法的RIETAN-2000 程序对所得实验结果进行了晶体结构精修,通过最大熵方法(MEM)解析得到了粉末晶体的等高电子密度分布三维(3D) 和二维(2D)可视化图谱。结果表明,各原子Bi(1)、Bi(2)、O(1)、O(2)和O(3)的原子热振动各向同性温度因子分别为0.004 938 nm2、0.004 174 nm2、0.007 344 nm2、0.007 462 nm2、和0.007 857 nm2,等高电子密度分布的可视化,进一步验证了晶体结构模型和原子位置的准确性,这些参数对研究晶体材料的热性质具有一定参考意义。 相似文献
5.
Shahzeb Ahmad Shazia Bashir Mahreen Akram Rizwan Amir Muhammad Shahid Rafique Wolfgang Husinsky Mubashir Javed 《Surface and interface analysis : SIA》2023,55(2):113-126
The present paper reports the investigation of surface morphology, elemental composition, phase changes and field emission properties of Si ion irradiated nickel (Ni) and titanium (Ti). The Ni and Ti targets have been irradiated with 500 keV Si ions generated by Pelletron accelerator at various fluences ranging from 6.9 × 1013 to 77.1 × 1013 ions/cm2. Stopping range of ions in matter analysis revealed higher values of electronic stopping and sputtering yield for Ni as compared with Ti. For both irradiated metals, electronic energy loss dominant over the nuclear stopping. The growth of induced surface structures have been analysed by using field emission scanning electron microscopy (FESEM) analysis. In case of Ni, as the ion fluence increases from 6.9 × 1013 to 65.8 × 1013 ions/cm2, the formation of spherical particulates, agglomers and sputtering is observed. Although in the case of Ti, with the increase of Si ion fluence from 11.6 × 1013 to 77.1 × 1013 ions/cm2, the formation of irregular-shaped particulates along with crater and sputtered channels is observed. X-ray diffraction (XRD) analysis shows that no new phase is identified. However, a significant increase in peak intensity is observed with increasing ion fluence. The variation in crystallite size and dislocation line density is also observed as a function of Si ion fluence. Fourier transform infrared spectroscopy analysis shows that no bands are formed after the Si ion irradiation. Field emission properties of ion-structured Ni and Ti are well correlated with the growth of surface structures observed by SEM and dislocation line density evaluated by XRD analysis. 相似文献
6.
Inspired by the promising potential of re-configurable intelligent surface (RIS)-aided transmission in achieving the vision of 6th Generation (6G) network, we analyze the security model for a vehicular-to-infrastructure (V2I) network by considering multiple RISs (M-RIS) on buildings to act as passive relays at fixed distances from a source. In addition, multiple eavesdroppers are presented in the vicinity of the intended destination. Our aim is to enhance the secrecy capacity (SC) and to minimize secrecy outage probability (SOP) in presence of multiple eavesdroppers with the help of M-RIS in V2I communications. We propose a key-less physical layer security using beam-forming by exploiting M-RIS. The proposed approach assumes the concept of detecting eavesdroppers before the information can be transmitted via beam-forming by utilizing M-RIS. The results reveal that with consideration of M-RIS and beam-forming, the achievable SC and SOP performance is significantly improved while imposing minimum power consumption and fewer RIS reflectors. 相似文献
7.
In this paper, intelligent reflecting surface (IRS) technology is employed to enhance physical layer security (PLS) for spectrum sharing communication systems with orthogonal frequency division multiplexing (OFDM). Aiming to improve the secondary users’ secrecy rates, a design problem for jointly optimizing the transmission beamforming of secondary base station (SBS), the IRS’s reflecting coefficient and the channel allocation is formulated under the constraints of the requirements of minimum data rates of primary users and the interference between users. As the scenario is highly complex, it is quite challenging to address the non-convexity of the optimization problem. Thus, a deep reinforcement learning (DRL) based approach is taken into consideration. Specifically, we use dueling double deep Q networks (D3QN) and soft Actor–Critic (SAC) to solve the discrete and continuous action space optimization problems, respectively, taking full advantage of the maximum entropy RL algorithm to explore all possible optimal paths. Finally, simulation results show that our proposed approach has a great improvement in security transmission rate compared with the scheme without IRS and OFDM, and our proposed D3QN-SAC approach is more effective than other approaches in terms of maximum security transmission rate. 相似文献
8.
Massive multiple-input-multiple-output (Massive MIMO) significantly improves the capacity of wireless communication systems. However, large-scale antennas bring high hardware costs, and security is a vital issue in Massive MIMO networks. To deal with the above problems, antenna selection (AS) and artificial noise (AN) are introduced to reduce energy consumption and improve system security performance, respectively. In this paper, we optimize secrecy energy efficiency (SEE) in a downlink multi-user multi-antenna scenario, where a multi-antenna eavesdropper attempts to eavesdrop the information from the base station (BS) to the multi-antenna legitimate receivers. An optimization problem is formulated to maximize the SEE by jointly optimizing the transmit beamforming vectors, the artificial noise vector and the antenna selection matrix at the BS. The formulated problem is a nonconvex mixed integer fractional programming problem. To solve the problem, a successive convex approximation (SCA)-based joint antenna selection and artificial noise (JASAN) algorithm is proposed. After a series of relaxation and equivalent transformations, the nonconvex problem is approximated to a convex problem, and the solution is obtained after several iterations. Simulation results show that the proposed algorithm has good convergence behavior, and the joint optimization of antenna selection and artificial noise can effectively improve the SEE while ensuring the achievable secrecy rate. 相似文献
9.
《Arabian Journal of Chemistry》2022,15(1):103482
The red flour beetle, Tribolium castaneum, and the mold Aspergillus flavus are well known threats of stored grain commodities, causing nutritional loss and poisoning of stored products, respectively. T. castaneum has developed resistance against most insecticides, leading to the use of extensive amounts of synthetic insecticides to protect stored grains. Synthetic pesticides not only toxify the environment but also cause serious health issues in humans using pesticide treated grains. This study aimed to identify plant-based natural pesticides to control T. castaneum and A. flavus. Essential oils were extracted from fresh aerial parts of Chenopodium ambrosioides, Conyza sumatrensis, Erigeron canadensis, and Tagetes minuta through steam distillation and investigated for insecticidal and anti-fungal activities against adult T. castaneum and A. flavus, respectively. GC–MS analysis of C. sumatrensis revealed the presence of 37.7% cis-lachnophyllum ester, 13.4% germacrene D, and 21.6% limonene, whereas in E. canadensis the major compounds were limonene, germacrene D, and cis-lachnophyllum ester (43.4%, 12.9% and 5.9%, respectively). In bioassays with treated grain, C. sumatrensis and E. canadensis essential oils exhibited excellent toxicity against adult T. castaneum with LD50 of 3.7 and 5.6 mg per 10 g grains whereas in a fumigation bioassay they showed LD50 of 6.6 and 10.6 mg/L, respectively. The essential oils extracted from C. ambrosioides and E. canadensis exhibited good anti-fungal activity against A. flavus. Our findings suggest that essential oils of C. sumatrensis and E. canadensis can play an important role in protecting stored grains from T. castaneum and A. flavus contamination. 相似文献
10.
稀土作为我国战略性矿产资源,其安全问题一直是政府和学术界关注与研究的重要课题.建立了稀土安全的概念框架与评价体系,针对传统AHP中九标度法的不足,基于熵值法、加速遗传算法及扩充标度值的层次分析法,提出了一种改进的层次分析法(EV-AGA-EAHP),通过集成模糊C-均值聚类算法和模糊综合评价法,研究提出了一种模糊综合集成评价方法(EV-AGA-EAHP-FCM-FIJ),给出了集成算法及步骤,对2001-2013年我国稀土安全水平进行了评价,提出了保障我国稀土安全的建议. 相似文献